We will assume that you are a developer familiar with Silverlight for Windows Phone but wish to get up to speed on Windows 8 application development, and the challenges and solutions that may arise during your porting effort. We will be migrating the Khan Academy Windows Phone 7 app developed by Joel Martinez.
The original source code for the phone app is here. The finished Windows 8 solution is also available for download.
Over the five instructional videos, you'll be taken through the SDK tools, data storage, Windows 8 interfaces, custom styling, and getting the app into the Windows Store.
You can get started over on Channel 9.